期刊
CHEMICAL SCIENCE
卷 3, 期 8, 页码 2639-2645出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2sc00583b
关键词
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资金
- National Science Foundation [DMR-0847758, CBET-0854414, CBET-0854465]
- National Institutes of Health [5R01HL092526-02, 5R21EB009909-02, 4R03AR056848-03]
- Department of Defense
- Oklahoma Center for Adult Stem Cell Research
- Oklahoma Center for the Advancement of Science and Technology [HR11-006]
- NATIONAL HEART, LUNG, AND BLOOD INSTITUTE [R01HL092526] Funding Source: NIH RePORTER
- NATIONAL INSTITUTE OF ARTHRITIS AND MUSCULOSKELETAL AND SKIN DISEASES [R03AR056848] Funding Source: NIH RePORTER
- NATIONAL INSTITUTE OF BIOMEDICAL IMAGING AND BIOENGINEERING [R21EB009909, R21EB015190] Funding Source: NIH RePORTER
Biomimetic silica formation is strongly dependent on the presence of cationic amine groups which hydrolyze organosilicate precursors and bind to silicate oligomers. Since most biological species possess anionic surfaces, the dependence on amine groups limits utilization of biotemplates for fabricating materials with specific morphologies and pore structures. Here, we report a general aminopropyltriethoxysilane (APTES) directed method for preparing hollow silica with well-defined morphologies using varying biotemplates (proteins, viruses, flagella, bacteria and fungi). Control experiments, pH evolution measurements and Si-29 NMR spectroscopic studies have revealed a mechanism of the assembly of APTES on bio-surfaces with subsequent nucleation and growth of silica. The APTES assembly and nuclei formation on bio-surfaces ensured precise transcription of the morphologies of biotemplates to the resulting silica. This method could be extended to the preparation of other oxides.
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