期刊
CHEMICAL SCIENCE
卷 2, 期 3, 页码 389-399出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0sc00388c
关键词
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资金
- NSF [CHE-0808825, CHE-0924410]
- NIH [R01 GM 68825]
- DOE [DE-FG02-09ER16069]
- RHODIA Inc.
- NATIONAL INSTITUTE OF GENERAL MEDICAL SCIENCES [R01GM068825] Funding Source: NIH RePORTER
This perspective summarizes recent results, which demonstrate that stable carbenes can activate small molecules (CO, H-2, NH3 and P-4) and stabilize highly reactive intermediates (main group elements in the zero oxidation state and paramagnetic species). These two tasks were previously exclusive for transition metal complexes.
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