期刊
CHEMICAL SCIENCE
卷 2, 期 7, 页码 1305-1310出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1sc00140j
关键词
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资金
- Natural Sciences and Engineering Research Council (NSERC) of Canada
- University of Alberta
Boronic acid catalysis (BAC) was applied to the 1,3-transposition of allylic alcohols and the related Meyer-Schuster rearrangement of propargylic alcohols using highly electron deficient polyfluoroarylboronic acids as catalysts under mild metal-free conditions. A wide range of synthetically useful products are formed in E : Z selectivities superior to that of metal-catalyzed methods. A mechanism is proposed involving partial or full ionization into an allylic (or propargylic) carbocation, and additional possibilities for multicatalytic tandem reactions are exemplified.
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