期刊
CHEMICAL SCIENCE
卷 2, 期 6, 页码 1086-1089出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1sc00095k
关键词
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资金
- Gates Millennium
- Amgen
- NSF [CHE-0639094, CHE-0541745]
- California Institute of Technology
The preparation and synthetic applications of benzoquinone monoketal-derived N-tert-butanesulfinyl imines is described. These synthetically versatile intermediates undergo highly diastereoselective 1,2-addition reactions with organometallic reagents to provide 4-aminocyclohexadienones in good yields. The utility of this methodology is demonstrated in a six-step enantioselective synthesis of (-)-3-demethoxyerythratidinone.
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