期刊
CHEMICAL SCIENCE
卷 2, 期 7, 页码 1349-1355出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0sc00621a
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资金
- BBSRC
- HFSP
- Leverhulme Trust
- ERC
- EPSRC
- Biotechnology and Biological Sciences Research Council [BB/G014515/1] Funding Source: researchfish
- Engineering and Physical Sciences Research Council [EP/E036244/1] Funding Source: researchfish
- BBSRC [BB/G014515/1] Funding Source: UKRI
- EPSRC [EP/E036244/1] Funding Source: UKRI
A novel class of supramolecular hydrogels derived from amino sugars is reported, where the self-assembly of aromatic carbohydrate amphiphiles is driven by CH-pi interactions, rather than pi-pi stacking and H-bonding associated with gelators based on aromatic peptide amphiphiles. Spectroscopic data is provided as evidence for this mode of self-assembly and in silico studies revealed that a combination of CH-pi and T-stacking of the fluorenyl groups contribute to the formation of the aggregated structures.
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