期刊
CHEMICAL SCIENCE
卷 2, 期 9, 页码 1835-1838出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1sc00175b
关键词
-
资金
- NIGMS [GM72586]
- NIH [GM80442-S1, GM096749]
- NATIONAL INSTITUTE OF GENERAL MEDICAL SCIENCES [R01GM080442, R01GM072586] Funding Source: NIH RePORTER
Herein we report an enantioselective synthesis of complex cyclopentanones using aliphatic aldehydes and activated enones. With the combination of a chiral secondary amine and a chiral triazolium catalyst, high diastereoselectivity and excellent enantioselectivity can be achieved. We present evidence of a clear cooperative effect when these two catalysts are present simultaneously in the system.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据