期刊
CHEMICAL SCIENCE
卷 2, 期 4, 页码 807-810出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0sc00613k
关键词
-
资金
- NSF [CHE-0847273]
- GAANN fellowship
A catalytic enantioselective method for the propargylation of aldimines is described. A silver catalyst ligated by a bidentate phoshpine is utilized to provide good yields and high ee's for a variety of substrates. Homopropargylic sulfonamide products undergo facile silver-mediated cyclization to generate 2-pyrrolines, useful intermediates for alkaloid synthesis.
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