期刊
CHEMICAL SCIENCE
卷 1, 期 3, 页码 369-373出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0sc00220h
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资金
- JSPS [21245023]
- Grants-in-Aid for Scientific Research [21245023] Funding Source: KAKEN
Dinuclear Co-salen complexes (R,R)-(S,S)-1-4 were synthesized and compared with their mononuclear counterpart rac-5 to suggest that a bimetallic mechanism is in charge for the alternating copolymerization of propylene oxide with CO2 in the absence of onium salt while a monometallic mechanism is more probable in its presence.
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