期刊
JOURNAL OF MATERIALS CHEMISTRY B
卷 3, 期 27, 页码 5544-5552出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5tb00893j
关键词
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资金
- Birmingham Science City: Innovative Uses for Advanced Materials in the Modern World (West Midlands Centre for Advanced Materials Project 2)
- Advantage West Midlands (AWM)
- European Regional Development Fund (ERDF)
- EPSRC, UK [EP/H021388/1]
- Advantage West Midlands
- Centre of Excellence in Medical Engineering at King's College London
- Welcome Trust
- EPSRC [WT088641/Z/09/Z]
- Engineering and Physical Sciences Research Council [EP/H021388/1] Funding Source: researchfish
- EPSRC [EP/H021388/1] Funding Source: UKRI
We report on a versatile and time-efficient method to fabricate calcium phosphate (CaP) microcapsules by utilizing oil-in-water emulsion droplets stabilized with synthetic branched copolymer (BCP) as templates. The BCP was designed to provide a suitable architecture and functionality to produce stable emulsion droplets, and to permit the mineralization of CaP at the surface of the oil droplet when incubated in a solution containing calcium and phosphate ions. The CaP shells of the microcapsules were established to be calcium deficient hydroxyapatite with incorporated chlorine and carbonate species. These capsule walls were made fluorescent by decoration with a fluorescein-bisphosphonate conjugate.
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