4.6 Article

Cobalt selenide: a versatile cocatalyst for photocatalytic water oxidation with visible light

期刊

JOURNAL OF MATERIALS CHEMISTRY A
卷 3, 期 35, 页码 17946-17950

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ta04767f

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资金

  1. National Basic Research Program of China [2013CB632405]
  2. National Natural Science Foundation of China [21425309, 21173043]
  3. State Key Laboratory of NBC Protection for Civilian [SKLNBC2013-04K]
  4. Specialized Research Fund for the Doctoral Program of Higher Education [20133514110003]
  5. Department of Education of Fujian Province in China

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Cobalt selenide has been developed as an effective cocatalyst to decorate visible light photocatalysts, including WO3, BiVO4 and g-C3N4, establishing intense surface contact with substrates for the photocatalytic water oxidation reaction. Compared with CoOx and CoSx, CoSe2 is superior for improving the photocatalytic water oxidation activity due to the lower anionic electronegativity, which leads to dense adhesion and enables fast interfacial charge transfer for the water oxidation reaction.

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