期刊
JOURNAL OF MATERIALS CHEMISTRY A
卷 3, 期 43, 页码 21754-21759出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ta05781g
关键词
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资金
- National Natural Science Foundation of China [51472173, 51522208]
- Natural Science Foundation of Jiangsu Province [BK20140302, SBK2015010320]
- Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices
- Priority Academic Program Development of Jiangsu Higher Education Institutions
- Collaborative Innovation Center of Suzhou Nano Science and Technology
Research on sodium ion batteries has recently been revived. Attention is now placed on the development of high-capacity and stable electrode materials at low costs. Among them, compounds operating on the conversion mechanism represent a promising class of anode materials. Unfortunately, they are generally plagued by poor electrical conductivity and large volume changes during repeated cycling. In this study, we exploit a new type of composite material made of copper phosphide and Super P carbon black (CuP2/C) as a potential anode candidate. The final products consisted of crystalline CuP2 cores coated with carbon black nanoparticles on the surface. Electrochemical measurements and multiple ex situ studies demonstrate that CuP2/C composites are capable of fast and reversible sodiation and desodiation based on the conversion mechanism. They deliver a large capacity in excess of 500 mA h g(-1), high rate capability and decent short-term cycling stability. Our study suggests that these transition metal phosphides with a suitable carbon coating may hold great opportunities as anode materials for sodium ion batteries for effective and economical energy storage.
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