期刊
JOURNAL OF MATERIALS CHEMISTRY A
卷 3, 期 18, 页码 9565-9577出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ta00867k
关键词
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资金
- program for New Century Excellent Talents in University [NCET-12-0696]
- Leading Talents for Zhengzhou Science and Technology Bureau [131PLJRC649]
- program for University Innovative Talents of Science and Technology in Henan Province [2012HASTIT03]
- National Natural Science Foundation of China [51472102]
A novel graphitized porous carbon nanosphere (GPCNS) material obtained by a convenient simultaneous activation and graphitization route, which was realized by heating resorcinol-formaldehyde (RF) resin nanospheres immersed with ZnCl2 and FeCl3 in an inert atmosphere, has been reported. A high graphitization level was achieved through the catalytic graphitization by reduced Fe metal, and the hierarchically micro/mesoporous structure was produced in a controlled fashion by tuning the mass ratio of the activating agent ZnCl2 and a carbon precursor. An optimal sample of GPCNS-2 was prepared with a FeCl3/ZnCl2/RF mass ratio of 0.5 : 2 : 1, exhibiting a highly graphitized framework and uniform spherical morphology with an average diameter of similar to 500 nm, as well as well-interconnected micro/mesoporous structure with a large surface area of 1664.8 m(2) g(-1). Acting as an electrode material for a supercapacitor application in 6 M KOH electrolyte, GPCNS-2 displayed excellent electrochemical performance with a high specific capacitance of 402.5 F g(-1) at a current density of 1 A g(-1). Moreover, an electrochemical impedance spectroscopy test demonstrated that the low internal electrical resistance of GPCNS-2 contributed a superior rate capability of above 75% retention rate even at 50 A g(-1). Furthermore, the GPCNS-2 electrode possessed an outstanding cycling stability, and about 96% of its initial specific capacitance at 5 A g(-1) was maintained after 5000 cycles.
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