4.6 Article

Fully-solution-processed organic solar cells with a highly efficient paper-based light trapping element

期刊

JOURNAL OF MATERIALS CHEMISTRY A
卷 3, 期 48, 页码 24289-24296

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ta07154b

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资金

  1. Swedish Energy Agency
  2. Knut and Alice Wallenberg Foundation through a Wallenberg Scholar grant
  3. Knut and Alice Wallenberg Foundation through the project Power Papers

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We demonstrate the use of low cost paper as an efficient light-trapping element for thin film photovoltaics. We verify its use in fully-solution processed organic photovoltaic devices with the highest power conversion efficiency and the lowest internal electrical losses reported so far, the architecture of which - unlike most of the studied geometries to date - is suitable for upscaling, i.e. commercialization. The use of the paper-reflector enhances the external quantum efficiency (EQE) of the organic photovoltaic device by a factor of approximate to 1.5-2.5 over the solar spectrum, which rivals the light harvesting efficiency of a highly-reflective but also considerably more expensive silver mirror back-reflector. Moreover, by detailed theoretical and experimental analysis, we show that further improvements in the photovoltaic performance of organic solar cells employing PEDOT:PSS as both electrodes rely on the future development of high-conductivity and high-transmittance PEDOT:PSS. This is due optical losses in the PEDOT:PSS electrodes.

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