期刊
JOURNAL OF MATERIALS CHEMISTRY A
卷 3, 期 15, 页码 8091-8097出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ta06645f
关键词
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资金
- National Basic Research Program of China [2013CB733501]
- National Natural Science Foundation of China [91334203, 21176066]
- 111 Project of China [B08021]
- Fundamental Research Funds for the Central Universities of China
- project of FP7-PEOPLE-2013-IRSES [PIRSES-GA-2013-612230]
For the real industrial process of CO2 capture, it is still a great challenge for adsorbents to exhibit excellent CO2 adsorption capacity in the presence of water. By combining a pre-seeding process and a two-step temperature controlling crystallization, a zeolitic imidazolate framework (ZIF-8) shell is introduced on the commercial zeolite adsorbent (5A) core to produce a series of 5A@ZIF-8 composites with an enhanced surface hydrophobicity. Each 5A@ZIF-8 composite exhibits a dynamic hydrophobic hindrance effect for the separation of CO2 from the simulated humid flue gas (15% CO2 and 90% humidity at 298 K). Among these, the CO2 adsorption capacity and the CO2/H2O selectivity of 5A@ZIF-8(I) can be as high as 2.67 mmol g(-1) and 6.61, respectively, at the optimized adsorption time of 10 min. More importantly, over 10 adsorption-desorption cycles, there is almost no degradation of the adsorption performance. Therefore, the novel strategy of utilizing the dynamic hydrophobic hindrance effect through a core-shell structure would be a good solution for improving the CO2 separation performance in practical applications.
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