期刊
JOURNAL OF MATERIALS CHEMISTRY A
卷 3, 期 13, 页码 6884-6893出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ta00006h
关键词
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资金
- International Science and Technology Cooperation Program of China [2012DFG42100]
- Natural Science Foundation of China [21173190, 21473156]
- Doctoral Program of Higher Education of China [20110101130003]
- International Science and Technology Cooperation Program of Zhejiang Province [2013C24011]
- A*STAR Project [1220203049 (R279-000-370-305)]
MoS2/reduced graphene oxide (MoS2/rGO) composites are fabricated through a facile supramolecule-mediated hydrothermal route. The effects of the supramolecule (pillar[ 5] arene) on the microstructure and electrochemical lithium storage performance of the MoS2/rGO composites are investigated. It is found that the MoS2/rGO composites display a wrinkled thin flaky appearance, in which there are a lot of irregular pores and apertures. Few-layer MoS2 sheets are well dispersed and anchored on the rGO surface. When evaluated as a host material for lithium storage, the MoS2/rGO composite exhibits a much higher specific capacity of 1050-1140 mA h g(-1) with excellent cyclic performance and a significantly enhanced high-rate capability of 815-875 mA h g(-1) at a current density of 1000 mA g(-1) in comparison with the pristine MoS2. The improved performance can be ascribed to the robust composite structure and the better synergic effects between few-layer MoS2 and rGO sheets.
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