4.6 Article

Synthesis of highly electrochemically active Li2S nanoparticles for lithium-sulfur-batteries

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JOURNAL OF MATERIALS CHEMISTRY A
卷 3, 期 31, 页码 16307-16312

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ta04504e

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Carbothermal reduction of lithium sulfate below its melting point was used to produce sub-micron sized lithium sulfide particles which retain the morphology of the source particle. Using a lithium polysulfide-doped ether electrolyte, significantly enhanced activation of lithium sulfide could be accomplished in battery cells, achieving high discharge capacities up to 1360 mA h g(sulfur)(-1) at a 0.1C rate. Showing an economically viable and scalable reaction routine for future lithium-sulfur-batteries.

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