期刊
JOURNAL OF MATERIALS CHEMISTRY A
卷 3, 期 11, 页码 6096-6101出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ta07149b
关键词
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资金
- National Key Basic Research Program of China (973 Program) [2013CB834804, 2013CB632403]
- Ministry of Science and Technology of China [2012DFH40090]
- Natural Science Foundation of China [21273257, 21371175]
- Beijing Natural Science Foundation [2142033]
- CAS-Croucher Funding Scheme for Joint Laboratories
- Chinese Academy of Sciences (100 Talents Program)
Cobalt phosphide (Co2P) is found, for the first time, to be a novel cocatalyst for efficient photocatalytic hydrogen evolution for a system containing CdS nanorods as a photocatalyst and DL-mandelic acid as an electron donor in water. Under optimal conditions, the H-2-production rate can reach up to 19 373 mu molh(-1) g(-1) after 10 h of LED light irradiation. Meanwhile, DL-mandelic acid can be oxidized to benzoylformic acid by the photo-generated holes of CdS nanorods, providing a green and economic way to synthesize benzoylformic acid from DL-mandelic acid.
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