期刊
JOURNAL OF MATERIALS CHEMISTRY A
卷 3, 期 4, 页码 1498-1503出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ta04350b
关键词
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资金
- National Basic Research Program of China (973 Program) [2014CB239701]
- National Natural Science Foundation of China [21173120, 51382116]
- Natural Science Foundation of Jiangsu Province [BK2011030]
- Fundamental Research Funds for the Central Universities of NUAA [NP2014403]
A Ge-graphene-carbon nanotube composite electrode was constructed by germanium (Ge) nanoparticles anchored on reduced graphene oxide (Ge-RGO) intertwined with carbon nanotubes (CNT). In this unique structure, the graphene sheets improve the electrical conductivity and buffer severe volume changes. Additionally, the CNT mechanically binds together with Ge-RGO to maintain the integrity of the electrodes and stabilize the electric conductive network for the active Ge nanoparticles, leading to better cycling performance. As a result, the designed anode exhibits an outstanding energy capacity up to 863.8 mA h g(-1) at a current density of 100 mA g(-1) after 100 cycles and good rate performances of 1181.7, 1073.8, 1005.2, 872.0, 767.6, and 644.8 mA h g(-1) at current densities of 100, 200, 400, 800, 1600, and 3200 mA g(-1), respectively. Our results indicate that the hybrids exhibit considerably improved lithium storage performance.
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