期刊
JOURNAL OF MATERIALS CHEMISTRY A
卷 3, 期 35, 页码 18273-18278出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ta03632a
关键词
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资金
- 973 project [2015CB251103]
- NSFC [51472104, 21473075, 51272088]
- Defense Industrial Technology Development Program [B1420133045]
- Development Program of Science and Technology of Jilin Province, China [20140101093JC]
- National Found for Fostering Talents of Basic Science [J1103202]
- Graduate Innovation Fund of Jilin University [2015002]
A novel hybrid Na+/Li+ battery is established by using Li2RuO3 as the cathode, 1 M NaClO4 in 1 : 1 EC/PC solution as the electrolyte and metallic sodium as the anode. In the working voltages between 2.0 and 4.0 V, Li2RuO3 delivers a high discharge capacity of 168 mA h g(-1) under the current density of 0.1 A g(-1) and an excellent capacity retention of about 88.1% after 50 cycles. The cathode also exhibits superior rate capability and long-term cycle life, whose discharge capacity reaches 85 mA h g(-1) after 300 cycles at the current density of 1 A g(-1). Importantly, both Na+ and Li+ can reversibly intercalate/deintercalate into Li2RuO3 in the same manner as in the typical Li-ion half cell. In addition, ex situ X-ray diffraction patterns of the initial charge and discharge processes as well as after long electrochemical cycles are examined to study its structural evolution. Our studies provide a strong insight into the design and application of novel rechargeable batteries.
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