期刊
JOURNAL OF MATERIALS CHEMISTRY A
卷 3, 期 17, 页码 9179-9186出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ta04988h
关键词
-
资金
- National Research Foundation of Korea (NRF) - Ministry of Science, ICT and Future Planning (MSIP) of Korea [NRF-2010-0014992, NRF-2012M1A2A2671721, NRF-2012M3A7B4049986, NRF-2012M3A6A7054861, 2011-220-D00064]
- POSCO Fusion Technology Center for Materials
A HC(NH2)(2)PbI3 solar cell of perovskite structure based on TiO2 nanohelices has been developed. Well-aligned helical TiO2 arrays of different pitch (p) and radius (r), helix-1 (p/2 = 118 nm, r = 42 nm), helix-2 (p/2 = 353 nm, r = 88 nm) and helix-3 (p/2 = 468 nm, r = 122 nm), were grown on fluorine-doped tin oxide (FTO) glass by oblique-angle electron beam evaporation. HC(NH2)(2)PbI3 perovskite was deposited on the TiO2 nanohelices by a two-step dipping method. Helix-1 showed higher short-circuit current density (J(SC)), whereas helix-3 exhibited slightly higher open-circuit voltage (V-OC). HC(NH2)(2)PbI3 perovskite combined with helix-1 demonstrated an average power conversion efficiency of 12.03 +/- 0.07% due to its higher J(SC) compared to helix-2 and helix-3. The higher J(SC) of helix-1 could be attributed to its greater light scattering efficiency and higher absorbed photon-to-current conversion efficiency. In addition, despite having the longest pathway structure, helix-1 showed rapid electron diffusion, attributed to its higher charge injection efficiency due to the larger contact area between perovskite and TiO2. We have established that fine tuning of the interface between perovskite and the electron-injecting oxide is a crucial factor in achieving a perovskite solar cell of high performance.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据