期刊
JOURNAL OF MATERIALS CHEMISTRY A
卷 3, 期 22, 页码 11773-11781出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ta00887e
关键词
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资金
- National Natural Science Foundation of China [51164006, 51472180, 51272176]
- Key Project of Tianjin Municipal Natural Science Foundation of China [14JCZDJC32200, 13JCZDJC33900]
- LPMT
- CAEP [KF14006]
- Academic Innovation Funding of Tianjin Normal University [52XC1404]
- Training Plan of Leader Talent of University in Tianjin
- Scientific Research Foundation for Returned Overseas Chinese Scholars of State Education Ministry
- program of Thousand Youth Talents in Tianjin of China
Spinel Li4Ti5O12 performance highly depends on both the electronic and ionic conductivity, however, developing a low-cost strategy to improve its electronic and ionic conductivity still remains challenging. In this study, a facile cost-saving carbothermal reduction method is introduced to synthesize the microscaled spinel Li4Ti5O12 particles with the surface modification of Ti(III) using anatase-TiO2, Li2CO3, and acetylene black (AB) as precursors. Remarkably, this ingenious design can easily eliminate the influence of the residual carbon, and thus makes it possible to individually study the effect of the Ti(III) on the bulk Li4Ti5O12. To reveal the role of the Ti(III), the electronic conductivity and lithium-ion diffusion coefficient of the as-prepared materials were measured using a direct volt-ampere method, electrochemical impedance spectroscopy (EIS), and cyclic voltammetry (CV). The results indicate that the carbothermal reduction leads to the increased electronic and ionic conductivity of the spinel Li4Ti5O12. As a result, the modified Li4Ti5O12 exhibits an enhanced cyclic stability, improved rate capability, and high Coulombic efficiency. The carbothermal reduction mechanism discreetly clarified in this study is beneficial to improving Li4Ti5O12 performance for further commercial applications.
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