期刊
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
卷 644, 期 22, 页码 1451-1455出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/zaac.201800240
关键词
Fluorine; Rhenium; Phenylimido compounds; X-ray diffraction; NMR
资金
- Graduate School Fluorine as a key element of the Deutsche Forschungsgemeinschaft [GK 1582]
The reaction of [ReOCl3(PPh3)(2)] with an equivalent amount of 4-fluoroaniline gives the rhenium(V) complex [Re(NPhF)(NH2PhF)Cl-3(PPh3)] as the major product, whereas from a reaction with an excess of the aniline the dinuclear compound [{Re(NPhF)(NH2PhF)Cl-2(PPh3)}(2)O] was isolated. The addition of an excess of PPh3 to the [ReOCl3(PPh3)(2)]/4-fluoroaniline reaction mixture gives [Re(NPhF)Cl-3(PPh3)(2)] in good yields. The products were studied by NMR spectroscopy and X-ray diffraction.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据