期刊
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
卷 639, 期 1, 页码 19-21出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/zaac.201200443
关键词
Calcium; Amides; Transmetalation; Bis(trimethylsilyl)amide; Tetrahydropyran
Transmetalation of Sn[N(SiMe3)2]2 with calcium granules in tetrahydropyran (thp) yields colorless [(thp)2Ca{N(SiMe3)2}2] (1) which is soluble in common organic solvents. The calcium center is in a distorted tetrahedral environment with CaN and CaO bond lengths of 231.08(11) and 240.23(9) pm, respectively. The molecular structure is dominated by steric factors leading to a NCaN bond angle of 119.43(6)degrees.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据