期刊
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
卷 639, 期 1, 页码 187-192出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/zaac.201200341
关键词
Bisimidazole ligand; Interpenetration; Zinc; Coordination polymers
资金
- Natural Scientific Research Foundation of Shaanxi Provincial Education Office [11JK0590]
- Natural Science Foundation of Shaanxi Province [2009JZ001]
- National Science Fund for Fostering Talents in Basic Science [J1210057]
- State Key Program of National Natural Science of China [20931005]
Two coordination polymers (CPs), {[Zn2(BMB)(5-AIPA)2]center dot 2H2O}n(1) and [Zn(BMB)(5-NIPA)]n(2) {BMB = 1, 4-bis[(2-methyl-imidazol-1-yl)methyl]benzene, 5-AIPA = 5-aminoisophthalic acid, 5-NIPA = 5-nitroisophthalic acid}, were synthesized under hydrothermal conditions. Compound 1 displays a 2D double-layer structure, which is packed into a 3D supramolecule by interlayer hydrogen bonds and pp stacking interactions. Compound 2 displays a threefold interpenetrating 3D network, which is composed of left-handed helical chains and two types of meso-helical chains along different directions.
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