4.1 Article

Alkaline Earth Metal Salts of 5,5′-Bistetrazole - from Academical Interest to Practical Application

期刊

出版社

WILEY-BLACKWELL
DOI: 10.1002/zaac.201100263

关键词

Alkaline earth metals; Tetrazoles; Crystal structures; IR spectroscopy; Pyrotechnics

资金

  1. Ludwig Maximilian University of Munich (LMU)
  2. U.S. Army Research Laboratory (ARL)
  3. Armament Research, Development and Engineering Center (ARDEC)
  4. Strategic Environmental Research and Development Program (SERDP)
  5. Office of Naval Research (ONR Global) [W911NF-09-2-0018, W911NF-09-1-0120, W011NF-09-1-0056, 10 WPSEED01-002 / WP-1765]
  6. The Cusanuswerk

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The alkaline earth metal salts of 5,5 '-BT, [Be(H(2)O)(4)](5,5 '-BT)center dot H(2)O (1), [Mg(H(2)O)(6)(5,5 '-BT)center dot 3H(2)O (2), [Ca(H(2)O)(4)(5,5 '-BT)]center dot H(2)O (3), [Sr(H(2)O)(4)(5,5 '-BT)]center dot 2DMF (4), and [Ba(H(2)O)(4)(5,5 '-BT)] (5) were fully characterized by low temperature X-ray diffraction, vibrational (IR, Raman) and NMR spectroscopy, elemental analysis and differential scanning calorimetry (DSC). A detailed description of the crystal structures is given. In addition, the potential use of 4 and 5 in coloring pyrotechnical compositions was investigated.

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