期刊
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
卷 634, 期 14, 页码 2643-2648出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/zaac.200800278
关键词
Hydrothermal synthesis; Crystal structure; 4,5-imidazoledicarboxylate; Luminescence; Hydrogen bonds
资金
- Chenguang Young Scientists of Wuhan [200850731361]
- Hubei Provincical Department of Education [Q20082601]
Three inorganic-organic hybrid frameworks [Mn(HIMDC)(4,4'-bipyo)(0.5)(H2O)](n) (1), [Cd(H2IMDC)(2)(2,2'-bipyo)] (2) and [Ca(HIMDC)(H2O)(2)center dot H2O](n) (3) (H3IMDC = 4,5-imidazoledicarboxylate 4,4'-bipyo = 4,4'-bipyridine-N,N'-dioxide; 2,2'-bipyo = 2,2'-bipyridine-N,N'-dioxide) have been hydrothermally synthesized and characterized by the elemental analyses, IR spectra, TG analysis and the single crystal diffraction. Both compounds 1 and 3 exhibit 2D layers while 2 is a monomer. It is noteworthy that compound 2 exhibits strong fluorescent emission in the solid state at room temperature.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据