4.3 Article

A New Equation Relating the Viscosity Arrhenius Temperature and the Activation Energy for Some Newtonian Classical Solvents

期刊

JOURNAL OF CHEMISTRY
卷 2015, 期 -, 页码 -

出版社

HINDAWI LTD
DOI: 10.1155/2015/163262

关键词

-

向作者/读者索取更多资源

In transport phenomena, precise knowledge or estimation of fluids properties is necessary, for mass flow and heat transfer computations. Viscosity is one of the important properties which are affected by pressure and temperature. In the present work, based on statistical techniques for nonlinear regression analysis and correlation tests, we propose a novel equation modeling the relationship between the two parameters of viscosity Arrhenius-type equation, such as the energy (E-a) and the preexponential factor (A(s)). Then, we introduce a third parameter, the Arrhenius temperature (T-A), to enrich the model and the discussion. Empirical validations using 75 data sets of viscosity of pure solvents studied at different temperature ranges are provided from previous works in the literature and give excellent statistical correlations, thus allowing us to rewrite the Arrhenius equation using a single parameter instead of two. In addition, the suggested model is very beneficial for engineering data since it would permit estimating the missing parameter value, if a well-established estimate of the other parameter is readily available.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.3
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

暂无数据
暂无数据