CuO, ZrO2 and ZnO nanoparticles as antiwear additive in oil lubricants

This work presents and discusses the antiwear behaviour of nanoparticle suspensions in a polyalphaolefin (PAO 6). CuO, ZnO and ZrO2 nanoparticles were separately dispersed at 0.5%, 1.0% and 2.0%wt. in PAO 6 using an ultrasonic probe for 2 min. AW properties were obtained using a TE53SLIM tribometer with a block-on-ring configuration. Tests were made under a load of 165 N, sliding speed of 2 m/s and a total distance of 3.066 m. Wear surfaces were analysed by scanning electron microscopy (SEM) and energy dispersive spectrometry (EDS) after wear tests. The study led to the following conclusions: all nanoparticle suspensions exhibited reductions in friction and wear compared to the base oil; the suspensions with 0.5% of ZnO and ZrO2 had the best general tribological behaviour, exhibiting high friction and wear reduction values even at low deposition levels on the wear surface; CuO suspensions showed the highest friction coefficient and lowest wear per nanoparticle content of 2%; and the antiwear mechanism of nanoparticulate additive was produced by tribo-sintering. (C) 2007 Elsevier B.V. All rights reserved.