期刊
WATER RESEARCH
卷 45, 期 4, 页码 1711-1719出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.watres.2010.11.022
关键词
Municipal solid waste (MSW) leachate; Dissolved organic matter (DOM); Heavy metal; Fluorescence excitation-emission matrix (EEM) quenching; Parallel factor (PARAFAC) analysis
资金
- National Basic Research Program of China (973 Program) [2011CB201504]
- National Natural Science Foundation of China [20807031]
- Ministry of Education [20090072120068]
Dissolved organic matter (DOM) plays an important role in heavy metal migration from municipal solid waste (MSW) to aquatic environments via the leachate pathway. In this study, fluorescence excitation-emission matrix (EEM) quenching combined with parallel factor (PARAFAC) analysis was adopted to characterize the binding properties of four heavy metals (Cu, Pb, Zn and Cd) and DOM in MSW leachate. Nine leachate samples were collected from various stages of MSW management, including collection, transportation, incineration, landfill and subsequent leachate treatment. Three humic-like components and one protein-like component were identified in the MSW-derived DOM by PARAFAC. Significant differences in quenching effects were observed between components and metal ions, and a relatively consistent trend in metal quenching curves was observed among various leachate samples. Among the four heavy metals, Cu(II) titration led to fluorescence quenching of all four PARAFAC-derived components. Additionally, strong quenching effects were only observed in protein-like and fulvic acid (FA)-like components with the addition of Pb(II), which suggested that these fractions are mainly responsible for Pb(II) binding in MSW-derived DOM. Moreover, the significant quenching effects of the FA-like component by the four heavy metals revealed that the FA-like fraction in MSW-derived DOM plays an important role in heavy metal speciation; therefore, it may be useful as an indicator to assess the potential ability of heavy metal binding and migration. (C) 2010 Elsevier Ltd. All rights reserved.
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