期刊
WASTE MANAGEMENT & RESEARCH
卷 28, 期 12, 页码 1122-1132出版社
SAGE PUBLICATIONS LTD
DOI: 10.1177/0734242X09360366
关键词
Fly ash; bottom ash; rice husk ash; dissolution-precipitation; zeolites; ammonium exchange capacity
资金
- Graduate Student Institute, Chiang Mai University
- Sustainable Infrastructure Research Development Centre (SIRDC), Khon Kaen University
Synthesis of zeolites from combustion by-products, including fly ash, bottom ash and rice husk ash, was studied. A molar ratio of SiO2/Al2O3 of 1.5 was used for the syntheses. Refluxing and hydrothermal methods were also used for synthesis for comparison. The reaction temperatures of refluxing and hydrothermal methods were 100 degrees C and 130 degrees C, respectively. Sodalite, phillipsite-K, and zeolite P1 with analcime were obtained when fly ash, bottom ash and rice husk ash were used as starting materials, respectively. With rice husk ash as a starting material, zeolite P1 was produced. This result had advantages over previous studies as there was no prior activation required for the synthesis. The concentrations and types of alkaline used in the synthesis also determined the zeolite type. The different zeolites obtained from three systems were measured for specific surface area and pore size by using BET and Hg-porosimetry, respectively. Ammonium exchange capacities of the synthesised powders containing zeolites, sodalite, zeolite P1 and phillipsite-K were 38.5, 65.0 and 154.7 meq 100 g (1), respectively.
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