Gamma ray induced changes on vibrational spectroscopic properties of strontium alumino-borosilicate glasses

The present investigation reports the effect of influence of aluminum ions on radiation damage of strontium borosilicate glasses studied by means of spectroscopic (viz., optical absorption (OA), infrared and Raman spectra). The composition of the glasses chosen for the study is 40SrO-xAl(2)O(3)-(15-x) B2O3 -40SiO(2) (X = 5, 7.5, 10), all in mol%. The glasses were synthesized by conventional melt quenching method. Later, the samples were exposed to gamma (gamma) radiation dose of strengths 10 kGy and 30 kGy with a dose rate of 1.5 Gy/s using Co-60 as radiation source. The infrared spectra (IR), Raman spectra and optical absorption (OA) spectra of the samples were recorded at ambient temperature before and after irradiation. The OA spectra of the pre-irradiated samples do not exhibit any absorption bands in the UV-vis regions and IR and Raman spectra exhibited conventional vibrational bands due to different borate, silicate AlO4 and AlO6 structural units. The OA spectra of post irradiated samples exhibited a broad absorption band in the wavelength region 600-750 nm; it is attributed to electron trapped color centers. The intensity of this peak is observed to increase with increase of the gamma-ray dose. Considerable changes in the intensities of various bands in the IR and Raman spectra were also observed. The changes were explained based on structural modifications taking place in the glass network due to gamma-ray irradiation and finally it is concluded that the glasses mixed with 10.0 mol% of Al2O3 are relatively more radiation resistant. (C) 2013 Elsevier B.V. All rights reserved.