期刊
ULTRASONICS SONOCHEMISTRY
卷 20, 期 5, 页码 1168-1175出版社
ELSEVIER
DOI: 10.1016/j.ultsonch.2013.02.002
关键词
Bunker-C oil; Ultrasound assisted; Oxidative desulfurization; Mass transfer; Batch processing
资金
- marine & Ports Authority (MPA) of Singapore [R09-003-1]
- Key Project Fund of Science and Technology Agency, Sichuan province [2013JY0128]
- Key Project Fund of Science and Technology bureau, Leshan, China
This work investigated the ultrasonic assisted oxidative desulfurization of bunker-C oil with TBHP/MoO3 system. The operational parameters for the desulfurization procedure such as ultrasonic irradiation time, ultrasonic wave amplitude, catalyst initial concentration and oxidation agent initial concentration were studied. The experimental results show that the present oxidation system was very efficient for the desulfurization of bunker-C oil and similar to 35% sulfur was removed which was dependent on operational parameters. The application of ultrasonic irradiation allowed sulfur removal in a shorter time. The stronger the solvent polarity is, the higher the sulfur removal rate, but the recovery rate of oil is lower. The sulfur compounds in bunker-C oil reacted with TBHP to produce corresponding sulfoxide, and further oxidation produced the corresponding sulfone. (C) 2013 Elsevier B.V. All rights reserved.
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