期刊
ULTRASONICS
卷 51, 期 2, 页码 202-209出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.ultras.2010.08.004
关键词
Sonoelectrochemistry; Mechanism of sonochemical effect; Microjets; Acoustic streaming; Sono-electrochemical cell design
An overview of possible mechanisms by which sonication can influence electrochemical processes is given. Four mechanisms are discussed: - acoustic streaming; - microstreaming and turbulence due to cavitation; - formation of microjets in the course of collapse of cavitation bubble; - shock waves; and possible effects are illustrated on several examples. The most effective process is formation of microjets, which can not only decrease diffusion layer thickness under 1 mu m, but also activate (depassivate) electrode surface. Design of experimental arrangement with maximum participation of microjets is proposed. Two approaches are proposed: - focusing of ultrasound on the working electrode and reduction of energy losses by over-pressure; -tuning the reactor to obtain resonance, i.e. formation of stationary waves by activating reactor in its resonant mode. (C) 2010 Elsevier B. V. All rights reserved.
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