期刊
ASIAN JOURNAL OF ORGANIC CHEMISTRY
卷 4, 期 7, 页码 622-625出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ajoc.201500148
关键词
aldehydes; alkylation; decarbonylation; Heck reaction; oxidation
资金
- National Science Foundation of China [21272267]
- State Key Laboratory of Heavy Oil Processing [SKLOP201401001]
- Renmin University of China [10XNL017]
- Beijing National Laboratory for Molecular Sciences (BNLMS)
- Fundamental Research Funds for the Central Universities
An alkyl-Heck-type cross-coupling reaction is developed by manganese-catalyzed oxidative decarbonylation of aldehydes. A variety of primary, secondary, and tertiary aliphatic aldehydes can participate in this alkenylation. The reaction is initiated by an alkyl radical, which is generated by oxidative decarbonylation of the aldehyde.
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