期刊
TRIBOLOGY LETTERS
卷 36, 期 2, 页码 175-182出版社
SPRINGER/PLENUM PUBLISHERS
DOI: 10.1007/s11249-009-9472-0
关键词
Inorganic fullerene
资金
- Harold L. Perlman Foundation
- Gurwin Fund
- Horowitz Foundation
- Irving and Cherna Moskowitz Center for Nano and Bio-Nano Imaging and NanoMaterials Ltd
- ERC [INTIF 226639]
- Israel Science Foundation
- Nationale de la Recherche (ANR)
Using a new quartz-made reactor, large amounts of fullerene-like (IF) MoS2 nanoparticles were synthesized by reacting MoO3 vapor with H2S in a reducing atmosphere. The nanoparticles were found to be of high crystalline order; with an average size of 70 nm and consist of more than 30 closed shells. Extensive tribological testing of the nanoparticles in two types of synthetic oils- poly-alpha olefins (PAO)- was carried out and compared to that of bulk (2H platelets) MoS2 and IF-WS2. These tests indicated that under high pressure and relatively low humidity, the IF-MoS2 exhibited a friction coefficient as low as 0.03 and the smallest wear rate of the measured systems. However, its performance was found to be lower in comparison to IF-WS2 after 2500 cycles, due probably to its inferior chemical stability. This study indicates that the tribological performance of the IF nanoparticles depends strongly on their crystalline order and size.
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