期刊
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
卷 4, 期 1, 页码 18-34出版社
AMER CHEMICAL SOC
DOI: 10.1021/acssuschemeng.5b01202
关键词
Selectivity; C-H bond activation; High-valent iron; Syntheses; Pollutants; Mechanism; Remediation; Toxicity
资金
- United States National Science Foundation [CBET-1439314]
- Ministry of Education, Youth and Sports of the Czech Republic [LO1305]
- Technology Agency of the Czech Republic Competence Centres [TE01020218]
- Div Of Chem, Bioeng, Env, & Transp Sys [1439314] Funding Source: National Science Foundation
Iron is the most common metal by mass on earth and represents the basic element of industrial society. The usage of iron to synthesize consumer products and to remediate environment is an attractive approach. This perspective presents applications of the high-valent iron oxo compound (FeO42-)-O-VI (ferrate) in sustainable organic synthesis and treatment technology. In synthesizing organic molecules, C-H bond activation and selectivity are two basic ingredients of efficiency, which are attainable by ferrate. Examples of hydroxylation of hydrocarbons and conversion of alcohols to aldehyde/ketone are presented. In addition, many other organic molecules of amines, aniline, phenolic, and thiol functionalities can be oxidized by ferrate. This oxidation chemistry of ferrate is expedient in transforming pharmaceuticals, micropollutants in bodies of water with implications for human and ecological health. A wide range of micropollutants, which are commonly found in drinking water resources and wastewater effluents, can be efficiently oxidized by ferrate on a seconds to minutes time scale. These molecules include endocrine disruptors, antibiotics, beta-blockers, antidepressants, X-ray contrast media, and cosmetic products. The reaction pathways of transformation of the studied pharmaceuticals are discussed. The results of the evaluation of toxicity of the oxidized products are given. The reduced product of ferrate is the environmentally friendly and magnetic iron(III) oxide. Ferrate, as a green molecule, has true potential in sustainable production of organics and treating emerging pollutants in water.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据