期刊
ACS Sustainable Chemistry & Engineering
卷 3, 期 11, 页码 2619-2630出版社
AMER CHEMICAL SOC
DOI: 10.1021/acssuschemeng.5b00763
关键词
Cascade engineering; One-pot synthesis; Biomass conversion; gamma-Valerolactone; 1,4-Pentanediol; 2-Methyl tetrahydrofuran; Levulinic acid; Palladium; Copper; Zirconia; Kinetics
资金
- UGC
- R. T. Mody Distinguished Professor Endowment
- J. C. Bose National Fellowship of Department of Science and Technology, Gov't. of India
- Indira Gandhi Centre for Atomic Research, Kalpakkam, India
Synthesis of chemicals derived from biomass using heterogeneous catalysts with water as a solvent elegantly fits into the realm of sustainable chemistry. In this work, a novel heterogeneous palladium copper bimetallic catalyst supported on zirconia was synthesized and fully characterized. This catalyst was used in one-pot synthesis of gamma-valerolactone, 1,4-pentanediol, and 2-methyl tetrahydrofuran from levulinic acid and hydrogen using water as a solvent. The catalyst consists of 1% palladium and 29% copper supported on zirconia and is characterized per se and after reuse by using elemental analysis, FTIR, NH3-TPD, XRD, and BET surface area, XPS, SEM, and TEM analysis. This is the first ever report on the direct synthesis of 1,4-pentanediol and 2-methyl tetrahydrofuran using water as a solvent. Reaction mechanism and kinetic modeling was done to validate the experimental results. The results reported are thus a combination of synthesis of a novel catalyst with its full characterization, its application in a novel synthesis route, description of the synthesis mechanism and kinetic modeling, and proof of the robustness of the developed catalyst by reusing it for four catalytic cycles.
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