期刊
TRANSITION METAL CHEMISTRY
卷 37, 期 1, 页码 45-53出版社
SPRINGER
DOI: 10.1007/s11243-011-9555-2
关键词
-
资金
- Center of Excellence of Chemistry of University of Isfahan (CECUI)
The biomimetic epoxidation of alkenes catalyzed by tetraphenylporphyrinatomanganese(III) chloride, [Mn(TPP)Cl], immobilized on multiwall carbon nanotubes modified with 4-aminopyridine and 4-aminophenol is reported. These heterogenized catalysts were used as efficient and reusable catalysts for epoxidation of a variety of cyclic and linear alkenes with sodium periodate under mild conditions. The catalysts, [Mn(TPP)Cl@amine-MWCNT], were characterized by physico-chemical and spectroscopic methods. The effect of ultrasonic irradiation on these catalytic systems was also investigated. The catalysts were reused several times without loss of their activity.
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