期刊
TRANSITION METAL CHEMISTRY
卷 35, 期 4, 页码 427-435出版社
SPRINGER
DOI: 10.1007/s11243-010-9345-2
关键词
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资金
- University Grants Commission (Eastern Region), India
- DST
- CSIR
- UGC, New Delhi, India
A poly(3,6-dibenzaldimino N-vinyl carbazole) Pd(II) complex has been synthesized and characterized by physicochemical and spectroscopic techniques. The complex was found to be highly active toward hydrogenation reactions of various organic substrates under atmospheric pressure at ambient temperature. A tentative reaction mechanism is proposed on the basis of kinetic studies and isolation of reactive intermediates. The catalyst shows good conversion rates, thermal stability and recyclability.
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