期刊
TRANSITION METAL CHEMISTRY
卷 35, 期 2, 页码 213-220出版社
SPRINGER
DOI: 10.1007/s11243-009-9316-7
关键词
-
资金
- National Science Technology Foundation of China [2006BAC2A08]
- NJIT Scientific Research Foundation for Introduce Talents [KXJ 08033, KXJ 08034]
A series of chromium(III) Schiff base complexes immobilized on MCM-41 were prepared and characterized by various physicochemical and spectroscopic methods. The complexes were used for the selective oxidation of alcohols by 30% hydrogen peroxide without any organic solvent, phase transfer catalyst or additive. The immobilized complexes proved to be effective catalysts and generally exhibited much higher catalytic performance than their corresponding homogeneous analogs. The catalytic performance of the immobilized complexes was also found to be closely related to the Schiff base ligands used. Under the optimal reaction conditions, secondary alcohols, cyclic alcohols and benzyl alcohol were prevailingly oxidized to their corresponding ketones or aldehydes.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据