A future application of pulse plating - silver recovery from hydrometallurgical bottom ash leachant

In the current study, electrodeposition-redox replacement was applied to a hydrometallurgical solution with the main elements of Ca (13.8 g L-1), Al (4.7 g L-1), Cu (2.5 g L-1), Zn (1.2 g L-1), Fe (1.2 g L-1), S (1 g L-1), Mg (0.8 g L-1), P (0.5 g L-1) and Ag (3.5 ppm). The solution originated from the leaching experiment of incinerator plant bottom ash, which was dissolved into 2 M HCl media at T=30 degrees C. The resulting deposit on the electrode surface was analysed with SEM-EDS and the observed Ag/(Cu + Zn) ratio (0.3) indicated remarkable enrichment of silver on the surface, when compared to the ratio of these elements (Ag/(Cu+Zn)) in the solution (6.8 x 10(-5)). The enrichment of Ag vs. (Cu + Zn) could be demonstrated to increase ca. 4500 fold compared to the ratio of the elements in solution.