期刊
TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA
卷 22, 期 10, 页码 2517-2522出版社
ELSEVIER
DOI: 10.1016/S1003-6326(11)61494-5
关键词
lithium-ion battery; graphene; CoO; anode material; ultrasonic synthesis
资金
- Tongji University, China [4340142501]
- National Natural Science Foundation of China [51173135]
A facile ultrasonic method was used to synthesize CoO/graphene nanohybrids by employing Co-4(CO)(12) as a cobalt precursor. The nanohybrids were characterized by SEM, TEM and XPS, and the results show that CoO nanoparticles (3-5 nm) distribute uniformly on the surface of graphene. The CoO/graphene nanohybrids display high performance as an anode material for lithium-ion battery, such as high reversible lithium storage capacity (650 mA.h/g after 50 cycles, almost twice that of commercial graphite anode), high coulombic efficiency (over 95%) and excellent cycling stability. The extraordinary performance arises from the structure of the nanohybrids: the nanosized CoO particles with high dispersity on conductive graphene substrates are beneficial for lithium-ion insertion/extraction, shortening diffusion length for lithium ions and improving conductivity, thus the lithium storage performance was improved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据