期刊
TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA
卷 21, 期 11, 页码 2535-2541出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/S1003-6326(11)61047-9
关键词
sphalerite; galena; zinc (II); lead (II); oxidation; acidophilic bacteria
资金
- University of Ilorin, Ilorin-Nigeria
- Academy of Sciences for the Developing World, Trieste, Italy
- N.N.P.C. Abuja
Zn(II) and Pb(II) from Nigerian sphalerite and galena ores were bioleached by a mixed culture of acidophilic bacteria. The influences of pH and ferric ion on the bioleaching rates of sphalerite and galena were examined. The result shows that pH 2.1 and 2.7 are favourable for the leaching of Zn(II) and Pb(II) from sphalerite and galena, respectively. It was observed that the use of agarose-simulated media caused cells to excrete exopolymers containing ferric ions which enhanced oxidation. The oxidation equilibrium for sphalerite and galena took 3 and 4 d, respectively. About 38.3% sphalerite and 34.2% galena were leached within 1 d and approximately 92.0% Zn(II) and 89.0% Pb(II) were recovered in 5 d, respectively. The unleached residual products were examined by X-ray diffraction for sphalerite, revealing the presence of elemental sulphur(S), zinc sulphate (ZnSO(4)) and few traces of calcium aluminate (Ca(3)Al(2)O(6)). The XRD pattern also indicates the presence of elemental sulphur (S), lead sulphate (PbSO(4)) and few traces of itoite [Pb(S,Ge)(O,OH)(4)] and cobalt lead silicate [Pb(8)Co(Si(2)O(7))(3)] in the unleached galena ore.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据