期刊
TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA
卷 20, 期 1, 页码 115-118出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/S1003-6326(09)60106-0
关键词
phosphor; rare earth; surface diffusion method; photoluminescence properties
资金
- National Basic Research Program of China [2007CB613607]
Y2O3:Eu3+ phosphors were synthesized by the surface diffusion method (SDM). X-ray diffractometry (XRD), scanning electron microscopy (SEM), and energy dispersive spectrometry (EDS) were used to characterize the structure, morphology and component Of Y2O3:Eu3+ phosphors. The photoluminescent (PL) properties were also investigated. The results reveal that the PL intensity Of Y2O3:Eu3+ phosphors prepared by the surface diffusion method (SI)M) is much higher than that prepared by homogeneous co-precipitation. The luminescence efficiency of the sample (Y-0.997, Eu-0.003)(2)O-3 prepared by the SDM is almost 1.9 times that by homogeneous co-precipitation. The concentration of Eu3+ in the phosphor Y2O3:Eu3+ prepared by the surface diffusion can be reduced greatly owing to the activator, Eu3+ ions, distributing mainly in the outer layer of the phosphors where the photon generation process occurs.
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