期刊
TOPICS IN CATALYSIS
卷 57, 期 10-13, 页码 1042-1048出版社
SPRINGER/PLENUM PUBLISHERS
DOI: 10.1007/s11244-014-0268-6
关键词
C-C bond formation; Cerium oxide; Hydrogen transfer; Platinum
资金
- MEXT program Elements Strategy Initiative to Form Core Research Center, Japan
Transition metal-loaded metal oxides are tested for C-C self-coupling of 2-octanol to a higher ketone at 140 degrees C. Among various catalysts, Pt/CeO2 shows the highest activity and shows good reusability. Pt/CeO2 is effective for the self-coupling of various aliphatic secondary alcohols and alpha-alkylation of methyl ketones with aliphatic secondary alcohols. A possible reaction mechanism is discussed.
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