期刊
TOPICS IN CATALYSIS
卷 55, 期 7-10, 页码 680-687出版社
SPRINGER/PLENUM PUBLISHERS
DOI: 10.1007/s11244-012-9850-y
关键词
Noble metals; Doped nanoscopic fluorides; Sol-gel synthesis; Beta zeolite; Impregnation; Citral; Menthol
资金
- UEFISCDI [PN-II-ID-PCE-2011-3-0041, 321/2011]
- graduate school Fluorine as key element of Deutsche Forschungsgemeinschaft, DFG [GRK 1582]
Active and selective bifunctional Me(Ir, Pd)/beta zeolite and doped nanoscopic hydroxylated fluorides (0.1 % Pd (or Pt)/AlF3) catalysts were developed for the one-pot synthesis of menthols from citral. In the case of fluoride catalysts, the strong electron-withdrawing effect of the dominating fluoride environment depletes the metal surface from electrons and hence, favours the hydrogenation of the C=C bond to citronellal on both Pd and Pt-based catalysts.
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