4.4 Article Proceedings Paper

Li-doped MgO From Different Preparative Routes for the Oxidative Coupling of Methane

期刊

TOPICS IN CATALYSIS
卷 54, 期 16-18, 页码 1266-1285

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SPRINGER/PLENUM PUBLISHERS
DOI: 10.1007/s11244-011-9749-z

关键词

Li/MgO; [Li+O-]; Oxidative coupling of methane; OCM; Wet impregnation; Precipitation; Single source precursors; Mixed milling; Deactivation

资金

  1. Deutsche Forschungsgemeinschaft
  2. IMPRS (International Max Planck Research School) of the Fritz Haber Institute of the Max Planck Society

向作者/读者索取更多资源

Li-doped MgO was prepared on different preparative routes and with different loadings. The catalytic activity was found to decay for all catalysts for 40 h time on stream. A detailed structural analysis of 0.5 wt% Li-doped MgO showed heavy losses of Li, reduced surface area and grain growth. A correlation between these factors and the deactivation could not be found. The reaction temperature and the flow rate were found to be the main deactivation parameters.

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