4.4 Article

Selective Conversion of Ethane to Ethene via Oxidative Dehydrogenation Over Ca-doped ThO2 Using CO2 as Oxidant

期刊

TOPICS IN CATALYSIS
卷 54, 期 13-15, 页码 881-887

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SPRINGER/PLENUM PUBLISHERS
DOI: 10.1007/s11244-011-9696-8

关键词

Oxidative dehydrogenation; Ethane; Ethene; CO2; Solid solution; Thorium oxide; Ca doping

资金

  1. ETH Zurich [TH-09 06-2]

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Ca-doped ThO2, synthesized by solution combustion method was tested for dehydrogenation of ethane with CO2. Doping ThO2 with Ca resulted in the creation of oxide ion vacancies and an increased conversion of ethane compared to pure ThO2. On Th0.75Ca0.25O2 selectivity to ethene was 97 at 46% ethane conversion at 725 degrees C. Well-known reference catalysts like 5%Cr/TS-1 or OMS-2 showed significantly lower selectivity, but the former was more active under the same conditions.

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