期刊
TOPICS IN CATALYSIS
卷 53, 期 11-12, 页码 773-782出版社
SPRINGER/PLENUM PUBLISHERS
DOI: 10.1007/s11244-010-9463-2
关键词
Transesterification; Esterification; Sulfated zirconia; Biodiesel; Rapeseed oil
资金
- Ministry of Science and Technology, Thailand
- EPSRC [EP/F067372/1] Funding Source: UKRI
Simultaneous transesterification and esterification of rapeseed oil with methanol in the presence of myristic acid was investigated. The effect of reaction temperature (120, 150 and 170 A degrees C) and the effect of initial free fatty acid content in oil (0, 10 and 20 wt%) on reaction rate were studied. The catalysts were found to increase the rate of all reactions. Sulfated zirconia prepared by a solvent-free method exhibited higher activity in simultaneous reaction than the conventional method. The presence of 10 wt% free fatty acids in the triglyceride increased the reaction rate and the final total fatty acid methyl esters content, and suggests that a non-catalytic reaction may be feasible.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据