期刊
TOPICS IN CATALYSIS
卷 53, 期 19-20, 页码 1438-1445出版社
SPRINGER/PLENUM PUBLISHERS
DOI: 10.1007/s11244-010-9604-7
关键词
Ring opening; Decalin; Iridium; Platinum; Zeolites
Selective ring opening of decalin was investigated over various metal-modified zeolites in order to shed light on the key parameters affecting the selectivity to ring-opening products at low extent of cracking reactions. Ir-modified zeolites H-Y and H-Beta having different concentration and strength of acid sites were studied in a batch reactor at 250-310 A degrees C and 20-60 bar H(2) and their performance was compared with that of Pt-modified zeolites. The concentration of Bronsted acid sites, reaction temperature and hydrogen pressure were shown to be the crucial reaction parameters. To obtain high selectivity to formation of ring-opening products from decalin, mildly acidic Ir-modified Beta was the best choice when the reaction was carried out at temperature of 270 A degrees C or lower and at H(2) pressure of 60 bar. Under these conditions the selectivity and yield of ring-opening products exceeded 65 and 60%, respectively.
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